To change Pages to Home in Sitefinity backend go to Administration->BackendPages and edit title and properties of the the page called Pages (Actions menu -> Title & Properties) change title and title for search engines to "Home". I have tested this and it didn`t caused any problems since the title was just a resource value for PageResources: Pages. The resource value can be also changed in Administration-> Interface labels and Messages. I suggest doing a test run on this on a blank project.
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